Chiral self-sorting
WebSelf-sorting strategies are suitable and effective approaches for accomplishing more complex rotaxanes and catenanes based on orthogonal binding motifs. ... and chiral self-sorting into homochiral or heterochiral complexes. 40. Jędrzejewska H. Szumna A. Making a right or left choice: chiral self-sorting as a tool for the formation of discrete ... WebDec 1, 2016 · Highly selective chiral self‐sorting. The chiral self‐sorting behavior of large cubic [8+12] salicylimine cage compounds was investigated, revealing a high selectivity for the most symmetric ...
Chiral self-sorting
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WebMar 20, 2024 · Metal‐Induced Planar Chirality of Soft‐Bridged Binuclear Platinum (II) Complexes: 100% Phosphorescence Quantum Yields, Chiral Self‐Sorting, and Circularly Polarized Luminescence - Song - Angewandte Chemie International Edition - Wiley Online Library. Research Article. WebOct 27, 2024 · However, control over such chiral self-sorting is hard to achieve with a desired choice of outcome. Herein, we report anion templated high-fidelity chiral self-sorting during the coordination-driven self-assembly of [Pd 2 L 4] metal-organic cages, with a racemic mixture of an axially chiral ligand. Upon varying the counter-anions, the …
WebSelf-sorting is a spontaneous phenomenon that ensures the formation of complex yet ordered multicomponent systems and conceptualizes the design of artificial and … WebJul 11, 2024 · Chiral self-sorting and guest recognition of porous aromatic cages Authors Dong-Xu Cui # 1 , Yun Geng # 1 , Jun-Ning Kou 1 , Guo-Gang Shan 1 , Chun-Yi Sun 2 , Kun-Hao Zhang 3 , Xin-Long Wang 4 , Zhong-Min Su 1 5 Affiliations 1 Institute of Functional Materials, Department of Chemistry, Northeast Normal University, Changchun, Jilin, China.
WebMar 21, 2024 · This work reports chiral social self-sorting in the diastereoselective self-assembly of Pd 6 L 12 metal-organic cages with a racemic mixture of axially chiral bis … WebOct 1, 2024 · 2D Hexagonal Assemblies of Amphiphilic Double Helical Poly (phenylacetylene) Homopolymers with Enhanced Circularly Polarized Luminescence and Chiral Self‐Sorting October 2024 Angewandte Chemie...
WebARTICLE Chiral self-sorting and guest recognition of porous aromatic cages Dong-Xu Cui 1,4, Yun Geng 1,4, Jun-Ning Kou 1, Guo-Gang Shan 1, Chun-Yi Sun 1, Kun-Hao Zhang 2, Xin-Long Wang 1 & Zhong ...
WebJul 11, 2024 · The synthesis of ultra-stable chiral porous organic cages (POCs) and their controllable chiral self-sorting at the molecular and supramolecular level remains challening. Herein, we report the... the peak hotel castleton derbyshirethe peaking threw the door amination mspWebAug 31, 2014 · Such self-sorting requires that, according to equation (1), the strength of chiral discrimination (–Δ cd H), that is, the difference in the formation enthalpies of the racemic mixture (Δ f H ... the peak hudson yardWebIsaacs classified chiral self-sorting into two different kinds, 11 namely social and narcissistic chiral self-sorting, during which chiral molecules self-assemble in either … the peak in great falls mtWebJul 2, 2024 · a The self-sorting preparation of cage 1 from chiral subcomponent A as a single pair of enantiomers.b The conversion of cage diastereomer T 1 into T 2 upon fullerene binding. c 1 H NMR spectra of ... the peak hotel tellurideWeb1 day ago · Self-sorting, which makes use of orthogonal binding motifs, is a potent approach to combining non-identical parts with precise and adjustable control of their relative positions. ... particularly the self-sorting in metallosupramolecular polygons and cages 38, 39 and chiral self-sorting into homochiral or heterochiral complexes. 40 ... the peak in missoulaWebApr 21, 2024 · Chiral self-sorting of 4 a occurred by macrocyclization with para-phenylenediamine in the presence of para-toluenesulfonic acid. The homochiral structure (PP and MM) containing two N-hetero-ortho … the peak hotel fairbanks